Why is PDLC considered to be smart?

The smartness of PDLCs is a result of its ability to change its transparency (technically called the transmittance) when an electrical stimulus is applied to it. This is normally by way of an alternating voltage, which exerts an alternating electric field across the PDLC material.
Nevertheless, the PDLC is only as smart as the control system which stimulates the change, which can be driven by a push button switch, a light sensor, or a building automation system.

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Does PDLC smart glass conduct electricity?

No, the internal PDLC layer is plastic and does not conduct electricity, since it is electrically insulated. Rather, it behaves more like a capacitor, where the applied signal alternates between positive and negative voltages at the plates of the capacitor, causing an alternating electric field throughout the PDLC dielectric, which is what aligns the liquid crystals with the frequency of the signal (normally 50 Hz or 60 Hz).

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What is smart glass/film?

Smart glass/film is a switchable light control glass that turns a transparent glass to opaque instantaneously and vice versa.

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How does smart glass/film works?

Smart glass works via electrical signal through activation of switches, sensors etc. Liquid crystal molecules turn to allow light to pass through and glass becomes transparent. It is opaque when not activated.

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Why does PDLC require a polymer?

The polymer allows the liquid crystals to be embedded into a film, which can then be sandwiched between panels of glass or plastic. The polymer has constant optical properties which do not vary across its structure, and hence is considered isotropic.
In contrast, the liquid crystal itself is anisotropic, since its optical characteristics are not constant across its structure, but rather can vary under application of an electric field.

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What is the structure of PDLC glass?

PDLC smart glass is composed of :
Outermost panels of normal float glass (or sometimes acrylic) sandwiched around:
Inner panels of optically clear PET plastic (polyethylene terephthalate), sandwiched around:
ITO (Indium Tin Oxide) which is a transparent conductor, sandwiched around:
a PDLC core comprised of liquid crystal droplets, suspended in a polymer.

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How does PDLC smart glass work?

With no applied voltage, the liquid crystals are randomly oriented and scatter the light which enters. When an electrical signal is applied, the liquid crystals orient themselves parallel to each other, allowing light through.

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