Why is PDLC considered to be smart?

The smartness of PDLCs is a result of its ability to change its transparency (technically called the transmittance) when an electrical stimulus is applied to it. This is normally by way of an alternating voltage, which exerts an alternating electric field across the PDLC material.
Nevertheless, the PDLC is only as smart as the control system which stimulates the change, which can be driven by a push button switch, a light sensor, or a building automation system.

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What is the structure of PDLC glass?

PDLC smart glass is composed of :
Outermost panels of normal float glass (or sometimes acrylic) sandwiched around:
Inner panels of optically clear PET plastic (polyethylene terephthalate), sandwiched around:
ITO (Indium Tin Oxide) which is a transparent conductor, sandwiched around:
a PDLC core comprised of liquid crystal droplets, suspended in a polymer.

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Is smart glass/film available in irregular shapes?

Yes, smart glass/film is available in all irregular shapes as you want, including curved glass.

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How does PDLC smart glass work?

With no applied voltage, the liquid crystals are randomly oriented and scatter the light which enters. When an electrical signal is applied, the liquid crystals orient themselves parallel to each other, allowing light through.

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Which sectors are using PDLC glass?

Transportation
Architectural (residential and commercial)
Interior design
Retail advertising
Healthcare (i.e. hospitals and clinics, since the PDLC smart glass can replace unhygienic curtains and blinds which often carry microbes and germs, and this also improves air quality)
Banking, thanks to the privacy afforded to ATMs and as internal partitions
Hospitality, especially bathrooms, since more natural light can penetrate interior spaces lacking windows to the outside world.

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Are PDLCs only available as artificial materials?

Not at all; common examples of natural occurrences of liquid crystals include proteins, soaps, detergents, and even some types of clay.

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What is smart glass comprised?

Smart glass is a laminated glass comprising 2pcs of glass sandwiched in between by an EVA/PVB interlayer.

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