What are the major reasons for using PDLC smart glass?

Enhanced security (since the glass is shatter-proof thanks to the internal plastic lamination)
Privacy (thanks to the scattering of light, essentially hiding whatever is behind the smart glass)
Glare reduction (again thanks to the scattering effect)
Reduction of the carbon footprint of the building thanks to the solar control, which reduces HVAC needs, both in summer and in winter
Reduced colour fading of interior furnishings and artworks, thanks to the rejection of UV
Creative marketing, since when the PDLC smart glass is off, the scattering effect creates a screen upon which you can project images.

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Does PDLC smart glass become opaque?

No, the correct term is translucent, since light still gets through, albeit scattered in many directions. The glass would be opaque only if the light was blocked or absorbed.

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What is smart glass comprised?

Smart glass is a laminated glass comprising 2pcs of glass sandwiched in between by an EVA/PVB interlayer.

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What is a Liquid Crystal?

A liquid crystal is a hybrid between (i) a liquid which flows like a fluid and (ii) a crystal which is normally found as a solid, exhibiting short- or long-range symmetry.

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How does smart glass/film works?

Smart glass works via electrical signal through activation of switches, sensors etc. Liquid crystal molecules turn to allow light to pass through and glass becomes transparent. It is opaque when not activated.

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Why is PDLC considered to be smart?

The smartness of PDLCs is a result of its ability to change its transparency (technically called the transmittance) when an electrical stimulus is applied to it. This is normally by way of an alternating voltage, which exerts an alternating electric field across the PDLC material.
Nevertheless, the PDLC is only as smart as the control system which stimulates the change, which can be driven by a push button switch, a light sensor, or a building automation system.

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Is smart glass/film available in irregular shapes?

Yes, smart glass/film is available in all irregular shapes as you want, including curved glass.

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