Are PDLCs only available as artificial materials?

Not at all; common examples of natural occurrences of liquid crystals include proteins, soaps, detergents, and even some types of clay.

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How does smart glass/film works?

Smart glass works via electrical signal through activation of switches, sensors etc. Liquid crystal molecules turn to allow light to pass through and glass becomes transparent. It is opaque when not activated.

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What is a Liquid Crystal?

A liquid crystal is a hybrid between (i) a liquid which flows like a fluid and (ii) a crystal which is normally found as a solid, exhibiting short- or long-range symmetry.

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Why does PDLC require a polymer?

The polymer allows the liquid crystals to be embedded into a film, which can then be sandwiched between panels of glass or plastic. The polymer has constant optical properties which do not vary across its structure, and hence is considered isotropic.
In contrast, the liquid crystal itself is anisotropic, since its optical characteristics are not constant across its structure, but rather can vary under application of an electric field.

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Are the only states of PDLC just ON and OFF?

No, the transmittance (level of transparency) of the PDLC can be varied from 0% in the OFF state up to any value you want until you reach the maximum transmittance (normally 70% or 80%). This is done by simply altering the voltage from 0 VAC up to 70VAC, which is typically the maximum recommended voltage. This can be done electrically with a variable isolating transformer, or electronically with a switched-mode smart glass dimmer.

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Why does PDLC require a polymer?

The polymer allows the liquid crystals to be embedded into a film, which can then be sandwiched between panels of glass or plastic. The polymer has constant optical properties which do not vary across its structure, and hence is considered isotropic.
In contrast, the liquid crystal itself is anisotropic, since its optical characteristics are not constant across its structure, but rather can vary under application of an electric field.

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Which sectors are using PDLC glass?

Transportation
Architectural (residential and commercial)
Interior design
Retail advertising
Healthcare (i.e. hospitals and clinics, since the PDLC smart glass can replace unhygienic curtains and blinds which often carry microbes and germs, and this also improves air quality)
Banking, thanks to the privacy afforded to ATMs and as internal partitions
Hospitality, especially bathrooms, since more natural light can penetrate interior spaces lacking windows to the outside world.

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