Are PDLCs only available as artificial materials?

Not at all; common examples of natural occurrences of liquid crystals include proteins, soaps, detergents, and even some types of clay.

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Is smart glass/film available in irregular shapes?

Yes, smart glass/film is available in all irregular shapes as you want, including curved glass.

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What is the structure of PDLC glass?

PDLC smart glass is composed of :
Outermost panels of normal float glass (or sometimes acrylic) sandwiched around:
Inner panels of optically clear PET plastic (polyethylene terephthalate), sandwiched around:
ITO (Indium Tin Oxide) which is a transparent conductor, sandwiched around:
a PDLC core comprised of liquid crystal droplets, suspended in a polymer.

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What are the major reasons for using PDLC smart glass?

Enhanced security (since the glass is shatter-proof thanks to the internal plastic lamination)
Privacy (thanks to the scattering of light, essentially hiding whatever is behind the smart glass)
Glare reduction (again thanks to the scattering effect)
Reduction of the carbon footprint of the building thanks to the solar control, which reduces HVAC needs, both in summer and in winter
Reduced colour fading of interior furnishings and artworks, thanks to the rejection of UV
Creative marketing, since when the PDLC smart glass is off, the scattering effect creates a screen upon which you can project images.

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Why is PDLC considered to be smart?

The smartness of PDLCs is a result of its ability to change its transparency (technically called the transmittance) when an electrical stimulus is applied to it. This is normally by way of an alternating voltage, which exerts an alternating electric field across the PDLC material.
Nevertheless, the PDLC is only as smart as the control system which stimulates the change, which can be driven by a push button switch, a light sensor, or a building automation system.

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What is the structure of PDLC glass?

PDLC smart glass is composed of :
Outermost panels of normal float glass (or sometimes acrylic) sandwiched around:
Inner panels of optically clear PET plastic (polyethylene terephthalate), sandwiched around:
ITO (Indium Tin Oxide) which is a transparent conductor, sandwiched around:
a PDLC core comprised of liquid crystal droplets, suspended in a polymer.

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Does PDLC smart glass conduct electricity?

No, the internal PDLC layer is plastic and does not conduct electricity, since it is electrically insulated. Rather, it behaves more like a capacitor, where the applied signal alternates between positive and negative voltages at the plates of the capacitor, causing an alternating electric field throughout the PDLC dielectric, which is what aligns the liquid crystals with the frequency of the signal (normally 50 Hz or 60 Hz).

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